Table 6. Percent Accuracy of Surrogate Predictions for Soils
Table 6. Percent Accuracy of Surrogate Predictions for Soils | ||||||||||||||||||
Soil #1a | Soil #2b | Soil #3b | ||||||||||||||||
vacuum spike | water spike | vacuum spike | water spike | vacuum spike | water spike | |||||||||||||
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dichlorodifluoro- methane | 21 | 15 | 1 | 78 | 17 | 0 | 72 | 19 | 7 | 82 | 20 | 62 | 86 | 26 | 8 | 450 | 77 | 79 |
chloromethane | 65 | 13 | 2 | 86 | 7 | 0 | 79 | 16 | 7 | 92 | 11 | 63 | 94 | 22 | 9 | 140 | 11 | 24 |
vinyl chloride | 71 | 14 | 2 | 88 | 11 | 0 | 87 | 19 | 7 | 85 | 13 | 63 | 98 | 27 | 9 | 106 | 8 | 17 |
bromomethane | 78 | 9 | 1 | 94 | 11 | 0 | 99 | 7 | 5 | 99 | 12 | 61 | 105 | 18 | 5 | 420 | 11 | 38 |
chloroethane | 72 | 9 | 1 | 92 | 9 | 0 | 89 | 8 | 6 | 91 | 9 | 62 | 101 | 22 | 7 | 650 | 10 | 85 |
trichlorofluoro- methane | 65 | 13 | 2 | 90 | 9 | 0 | 88 | 10 | 8 | 80 | 9 | 63 | 99 | 28 | 9 | 860 | 16 | 146 |
diethyl ether | 340 | 350 | 34 | 510 | 200 | 23 | 117 | 12 | 9 | 560 | 240 | 190 | 340 | 330 | 12 | 970 | 52 | 80 |
acetone | 103 | 17 | 17 | 89 | 2 | 5 | 105 | 20 | 12 | 98 | 4 | 72 | 69 | 2 | 10 | 72 | 11 | 31 |
1,1-dichloroethene | 75 | 27 | 2 | 91 | 3 | 0 | 87 | 9 | 7 | 83 | 12 | 63 | 450 | 520 | 38 | 148 | 16 | 22 |
iodomethane | 85 | 6 | 1 | 94 | 5 | 0 | 112 | 7 | 4 | 104 | 16 | 61 | 104 | 15 | 4 | 106 | 3 | 7 |
allyl chloride | 70 | 7 | 1 | 86 | 6 | 0 | 85 | 7 | 5 | 90 | 10 | 62 | 91 | 16 | 6 | 113 | 5 | 13 |
methylene chloride-d6 | 93 | 2 | 5 | 95 | 5 | 2 | 103 | 4 | 3 | 104 | 6 | 65 | 109 | 4 | 1 | 99 | 3 | 2 |
methylene chloride | 91 | 3 | 6 | 96 | 5 | 2 | 100 | 5 | 3 | 106 | 5 | 64 | 106 | 2 | 1 | 106 | 4 | 2 |
acrylonitrile | NAg | 94 | 4 | 6 | NA | 108 | 5 | 70 | 110 | 7 | 17 | 74 | 5 | 34 | ||||
trans-1,2- dichloro- ethene | 81 | 9 | 1 | 101 | 8 | 0 | 94 | 4 | 3 | 107 | 10 | 61 | 101 | 17 | 4 | 118 | 7 | 8 |
1,1-dichloroethane | 87 | 2 | 2 | 92 | 4 | 1 | 100 | 2 | 1 | 97 | 2 | 62 | 101 | 3 | 1 | 56 | 0 | 0 |
methacrylonitrile | NA | 94 | 3 | 5 | NA | 145 | 14 | 74 | 99 | 4 | 5 | 66 | 1 | 5 | ||||
2-butanone | 119 | 12 | 17 | 89 | 9 | 5 | 136 | 21 | 15 | 98 | 4 | 74 | 69 | 13 | 10 | 66 | 4 | 28 |
propionitrile | NA | 82 | 3 | 4 | NA | 92 | 2 | 70 | 113 | 4 | 16 | 60 | 2 | 23 | ||||
2,2-dichloropropane | 75 | 5 | 1 | 95 | 1 | 0 | 87 | 4 | 5 | 87 | 5 | 63 | 87 | 10 | 5 | 112 | 1 | 13 |
cis-1,2-dichloro- ethene | 94 | 1 | 5 | 99 | 2 | 2 | 99 | 1 | 3 | 103 | 0 | 63 | 102 | 4 | 1 | 99 | 1 | 2 |
chloroform | 98 | 2 | 7 | 101 | 2 | 3 | 99 | 1 | 4 | 102 | 2 | 64 | 104 | 3 | 1 | 97 | 0 | 2 |
isobutanol | 134 | 10 | 25 | 97 | 8 | 6 | 128 | 7 | 17 | 95 | 5 | 68 | 85 | 13 | 13 | NA | ||
bromochloro- methane |
101 | 2 | 6 | 102 | 0 | 2 | 102 | 1 | 3 | 107 | 2 | 67 | 103 | 1 | 2 | 95 | 1 | 2 |
1,1,1-trichloroethane | 79 | 6 | 1 | 101 | 1 | 0 | 86 | 5 | 5 | 89 | 5 | 62 | 91 | 13 | 6 | 117 | 1 | 14 |
1,1-dichloropropene | 65 | 7 | 3 | 98 | 2 | 2 | 79 | 5 | 6 | 83 | 5 | 60 | 91 | 19 | 7 | 120 | 2 | 17 |
carbon tetrachloride | 75 | 8 | 2 | 107 | 4 | 0 | 84 | 7 | 7 | 89 | 6 | 62 | 93 | 20 | 8 | 121 | 2 | 18 |
benzene-d6 | 95 | 1 | 2 | 98 | 1 | 1 | 99 | 0 | 1 | 101 | 1 | 61 | 99 | 2 | 1 | 98 | 1 | 1 |
1,2-dichloroethane | 104 | 2 | 7 | 101 | 1 | 2 | 102 | 1 | 4 | 106 | 0 | 68 | 101 | 2 | 2 | 93 | 1 | 3 |
benzene | 85 | 2 | 2 | 99 | 1 | 1 | 95 | 0 | 1 | 102 | 1 | 61 | 98 | 1 | 2 | 99 | 1 | 1 |
trichloroethene | 103 | 2 | 2 | 111 | 3 | 1 | 98 | 5 | 4 | 106 | 1 | 61 | 99 | 8 | 4 | 105 | 2 | 7 |
1,2-dichloro- propane-d6 | 98 | 2 | 6 | 98 | 1 | 2 | 99 | 2 | 3 | 99 | 1 | 64 | 100 | 1 | 1 | 97 | 1 | 2 |
1,2-dichloropropane | 99 | 2 | 7 | 98 | 2 | 3 | 99 | 1 | 4 | 99 | 1 | 64 | 100 | 2 | 1 | 98 | 1 | 2 |
methyl methacrylate | 64 | 1 | 8 | 66 | 1 | 4 | 62 | 3 | 5 | 67 | 5 | 84 | 53 | 3 | 3 | 69 | 2 | 6 |
bromodichloromethane | 119 | 4 | 7 | 106 | 2 | 2 | 104 | 4 | 3 | 105 | 1 | 64 | 104 | 2 | 1 | 97 | 1 | 2 |
1,4-dioxane | 86 | 4 | 9 | 91 | 1 | 4 | 94 | 4 | 8 | 97 | 1 | 67 | 104 | 6 | 13 | 81 | 1 | 19 |
dibromomethane | 114 | 3 | 14 | 107 | 2 | 6 | 105 | 2 | 8 | 107 | 1 | 70 | 103 | 1 | 5 | 95 | 1 | 8 |
4-methyl-2-pentanone | 82 | 3 | 11 | 80 | 1 | 5 | 97 | 3 | 8 | 89 | 5 | 72 | 82 | 2 | 4 | 68 | 2 | 6 |
trans-1,3- dichloropropene | 111 | 1 | 9 | 101 | 1 | 3 | 105 | 1 | 5 | 101 | 0 | 63 | 102 | 1 | 2 | 99 | 1 | 2 |
toluene | 77 | 5 | 5 | 101 | 0 | 3 | 92 | 1 | 4 | 101 | 1 | 59 | 98 | 1 | 2 | 104 | 1 | 1 |
pyridine | 137 | 42 | 39 | 105 | 6 | 9 | 106 | 15 | 17 | 84 | 1 | 68 | 79 | 5 | 16 | 141 | 6 | 86 |
cis-1,3-dichloro-propene | 126 | 4 | 10 | 110 | 2 | 3 | 108 | 4 | 5 | 107 | 1 | 66 | 100 | 1 | 3 | 98 | 1 | 3 |
N-nitrosodi-methylamine | 93 | 11 | 12 | 147 | 10 | 8 | 110 | 5 | 10 | 184 | 38 | 65 | 113 | 13 | 6 | 510 | 30 | 42 |
1,1,2-trichloro-ethane-d3 | 111 | 3 | 15 | 105 | 3 | 6 | 98 | 3 | 8 | 100 | 4 | 70 | 93 | 2 | 5 | 98 | 1 | 8 |
2-hexanone | 88 | 5 | 12 | 80 | 4 | 4 | 113 | 3 | 8 | 91 | 3 | 68 | 90 | 3 | 5 | 69 | 4 | 6 |
1,1,2-trichloroethane | 120 | 3 | 16 | 107 | 2 | 6 | 106 | 4 | 9 | 104 | 2 | 68 | 101 | 0 | 5 | 97 | 1 | 8 |
tetrachloroethene | 98 | 16 | 5 | 102 | 7 | 2 | 99 | 14 | 6 | 95 | 2 | 57 | 98 | 18 | 6 | 81 | 5 | 9 |
1,3-dichloropropane | 103 | 1 | 14 | 101 | 1 | 6 | 99 | 1 | 8 | 99 | 1 | 67 | 99 | 1 | 5 | 97 | 1 | 8 |
dibromochloro-methane | 128 | 3 | 11 | 109 | 2 | 3 | 109 | 4 | 5 | 105 | 0 | 63 | 100 | 1 | 3 | 97 | 1 | 3 |
2-picoline | NA | 141 | 10 | 6 | NA | 152 | 47 | 63 | 51 | 25 | 5 | 161 | 22 | 40 | ||||
1,2-dibromoethane | 93 | 1 | 12 | 96 | 1 | 5 | 91 | 2 | 7 | 93 | 1 | 65 | 97 | 1 | 5 | 92 | 0 | 8 |
chlorobenzene | 100 | 3 | 9 | 104 | 1 | 4 | 97 | 1 | 5 | 103 | 1 | 56 | 99 | 1 | 2 | 96 | 1 | 2 |
1,1,1,2-tetrachloro-ethane | 115 | 2 | 10 | 104 | 1 | 3 | 107 | 1 | 3 | 103 | 1 | 58 | 102 | 1 | 2 | 102 | 1 | 2 |
ethylbenzene | 91 | 2 | 4 | 98 | 0 | 2 | 93 | 0 | 4 | 101 | 1 | 53 | 99 | 1 | 2 | 104 | 1 | 1 |
N-nitroso-methyl- ethylamine | 102 | 13 | 25 | 119 | 8 | 6 | 104 | 4 | 11 | 109 | 16 | 55 | 104 | 7 | 14 | 350 | 14 | 120 |
m,p-xylenes | 92 | 1 | 4 | 99 | 1 | 2 | 94 | 1 | 4 | 101 | 1 | 53 | 98 | 1 | 2 | 106 | 1 | 1 |
styrene | 111 | 3 | 9 | 103 | 1 | 3 | 101 | 2 | 6 | 104 | 1 | 53 | 102 | 1 | 1 | 104 | 0 | 3 |
o-xylene | 95 | 1 | 6 | 98 | 1 | 2 | 94 | 1 | 5 | 100 | 1 | 53 | 99 | 1 | 1 | 103 | 1 | 2 |
isopropylbenzene | 80 | 3 | 4 | 99 | 2 | 1 | 87 | 2 | 5 | 102 | 1 | 51 | 97 | 3 | 3 | 115 | 1 | 5 |
bromoform | 120 | 1 | 15 | 106 | 0 | 6 | 104 | 1 | 9 | 97 | 2 | 60 | 96 | 1 | 5 | 99 | 1 | 8 |
cis-1,4-dichloro-2-butene | 103 | 4 | 13 | 94 | 4 | 5 | 104 | 5 | 10 | 87 | 1 | 60 | 91 | 1 | 5 | 86 | 1 | 7 |
N-nitrosodiethylamine | 80 | 17 | 19 | 96 | 12 | 4 | 92 | 13 | 10 | 78 | 10 | 51 | 125 | 9 | 15 | 220 | 5 | 53 |
1,1,2,2-tetrachloro-ethane | 120 | 5 | 15 | 107 | 2 | 6 | 108 | 4 | 10 | 100 | 1 | 61 | 92 | 2 | 5 | 99 | 2 | 8 |
4-bromo-1-fluoro-benzene | 119 | 3 | 10 | 106 | 2 | 3 | 106 | 1 | 7 | 107 | 1 | 52 | 101 | 1 | 1 | 101 | 0 | 2 |
1,2,3-trichloro-propane | 90 | 15 | 23 | 90 | 5 | 5 | 86 | 0 | 7 | 83 | 1 | 59 | 87 | 1 | 5 | 87 | 1 | 7 |
n-propylbenzene | 94 | 11 | 19 | 100 | 3 | 1 | 93 | 6 | 5 | 105 | 0 | 50 | 99 | 5 | 4 | 118 | 1 | 7 |
trans-1,4-dichloro -2- butene | 125 | 12 | 31 | 97 | 4 | 5 | 107 | 0 | 9 | 88 | 2 | 59 | 92 | 1 | 5 | 84 | 1 | 7 |
1,3,5-trimethyl-benzene | 103 | 11 | 21 | 97 | 1 | 1 | 102 | 4 | 4 | 108 | 2 | 49 | 102 | 3 | 3 | 110 | 1 | 2 |
bromobenzene | 126 | 12 | 28 | 103 | 1 | 3 | 106 | 2 | 5 | 102 | 0 | 52 | 102 | 2 | 2 | 98 | 0 | 2 |
2- chlorotoluene | 117 | 12 | 24 | 102 | 1 | 1 | 108 | 6 | 4 | 111 | 3 | 50 | 107 | 2 | 3 | 106 | 1 | 1 |
4-chlorotoluene | 121 | 13 | 25 | 102 | 3 | 2 | 106 | 4 | 4 | 107 | 1 | 49 | 102 | 3 | 3 | 105 | 1 | 2 |
pentachloroethane | 138 | 19 | 30 | 114 | 2 | 3 | 121 | 8 | 6 | 116 | 4 | 53 | 105 | 3 | 3 | 138 | 8 | 3 |
tert-butulbenzene | 92 | 10 | 19 | 97 | 2 | 2 | 90 | 4 | 5 | 101 | 1 | 48 | 98 | 4 | 4 | 120 | 2 | 6 |
1,2,4-trimethyl-benzene | 103 | 10 | 22 | 96 | 1 | 2 | 99 | 3 | 5 | 104 | 2 | 48 | 101 | 1 | 3 | 110 | 1 | 3 |
sec-butylbenzene | 89 | 12 | 19 | 101 | 4 | 2 | 91 | 8 | 6 | 107 | 3 | 49 | 99 | 7 | 6 | 121 | 2 | 11 |
aniline | 210 | 64 | 113 | 94 | 14 | 9 | 116 | 10 | 33 | 70 | 14 | 52 | 129 | 19 | 31 | 680 | 36 | 450 |
p-isopropyl toluene | 95 | 18 | 41 | 96 | 2 | 3 | 95 | 12 | 24 | 99 | 3 | 47 | 94 | 3 | 8 | 115 | 2 | 9 |
1,3-dichlorobenzene | 139 | 17 | 31 | 106 | 3 | 3 | 116 | 6 | 7 | 114 | 1 | 49 | 103 | 3 | 4 | 100 | 1 | 4 |
1,4-dichorobenzene | 140 | 17 | 32 | 106 | 2 | 4 | 115 | 5 | 8 | 111 | 1 | 50 | 102 | 3 | 4 | 100 | 1 | 4 |
n-butylbenzene | 102 | 20 | 44 | 103 | 5 | 3 | 106 | 16 | 28 | 112 | 5 | 48 | 94 | 6 | 8 | 120 | 2 | 12 |
1,2-dichlorobenzene | 141 | 17 | 34 | 105 | 2 | 4 | 115 | 6 | 9 | 108 | 0 | 49 | 101 | 2 | 4 | 97 | 1 | 5 |
benzyl alcohol | 142 | 55 | 67 | 102 | 6 | 8 | 84 | 12 | 27 | 78 | 18 | 50 | 97 | 10 | 19 | 460 | 19 | 200 |
N-nitrosodi-n- propylamine | 115 | 36 | 55 | 83 | 11 | 6 | 108 | 27 | 34 | 54 | 8 | 49 | 106 | 16 | 17 | 93 | 3 | 33 |
acetophenone-d5 | 153 | 33 | 74 | 96 | 9 | 8 | 118 | 18 | 37 | 60 | 4 | 49 | 78 | 3 | 15 | 37 | 1 | 17 |
o-toluidine | 330 | 130 | 190 | 85 | 15 | 9 | 100 | 2 | 33 | 58 | 15 | 50 | 114 | 19 | 29 | 530 | 29 | 380 |
1,2-dibromo-3- chloropropane | 154 | 25 | 69 | 96 | 6 | 7 | 101 | 5 | 28 | 70 | 5 | 52 | 79 | 3 | 8 | 54 | 1 | 7 |
hexachlorobutadiene | 64 | 7 | 63 | 113 | 4 | 18 | 90 | 3 | 49 | 124 | 18 | 58 | 104 | 13 | 10 | 133 | 3 | 14 |
1,2,4-trichloro-benzene | 120 | 26 | 108 | 114 | 2 | 17 | 116 | 5 | 56 | 123 | 2 | 58 | 104 | 4 | 9 | 96 | 1 | 7 |
naphthalene-d8 | 114 | 23 | 129 | 114 | 6 | 22 | 94 | 6 | 58 | 92 | 4 | 58 | 96 | 4 | 9 | 71 | 1 | 6 |
naphthalene | 96 | 14 | 119 | 113 | 5 | 24 | 91 | 8 | 60 | 92 | 2 | 59 | 97 | 3 | 9 | 76 | 1 | 7 |
1,2,3-trichloro-benzene | 125 | 27 | 156 | 120 | 0 | 26 | 124 | 6 | 84 | 130 | 4 | 67 | 107 | 3 | 9 | 90 | 1 | 8 |
N-nitroso dibutylamine | 440 | 250 | 330 | 75 | 17 | 25 | 320 | 160 | 210 | 66 | 22 | 65 | 250 | 61 | 89 | 900 | 62 | 920 |
2-methy naphthalene | 1000 | 750 | 580 | 168 | 13 | 57 | 580 | 330 | 320 | 167 | 1 | 101 | 121 | 16 | 25 | 162 | 8 | 75 |
a Three replicate analyses were performed for both the water
and vacuum spike.
b Three replicate analyses were performed for both the water
and vacuum spike.
c Seven-replicate water spikes and three-replicate vacuum spikes
were performed.
d Average of replicate accuracy results using surrogate corrections.
e Standard deviation (1 sigma) of replicate analyses.
f Average variation between predictions of the surrogate pairs
for the replicate analyses.
g Analyte not significantly present in vacuum distillate